简介
McMurry (Cornell U.) presents this 7th edition introducing organic chemistry to undergraduates. Thirty chapters are organized primarily by functional group, from the most simple (alkanes) to the most complex. Concise text is supported by abundant illustrations and exercises. Sample topics include: stereochemistry, organohalides, structure determination using mass spectrometry and infrared spectroscopy, corbonyl condensation reactions, the four types of biomolecule, the organic chemistry of metabolic pathways, and synthetic polymers, among others. Updates include new coverage of noncovalent reactions, comparisons between biological reactions and laboratory reactions, chirality at phosphorus and sulfur, and terpenoid and steroid biosynthesis. Annotation 漏2007 Book News, Inc., Portland, OR (booknews.com)
目录
Solutions to Problems
Chapter 1 Structure and Bonding p. 1
Chapter 2 Polar Bonds and Their Consequences p. 17
Review Unit 1 p. 35
Chapter 3 Organic Compounds: Alkanes and Cycloalkanes p. 38
Chapter 4 Stereochemistry of Alkanes and Cycloalkanes p. 59
Chapter 5 An Overview of Organic Reactions p. 84
Review Unit 2 p. 100
Chapter 6 Alkenes: Structure and Reactivity p. 104
Chapter 7 Alkenes: Reactions and Synthesis p. 126
Chapter 8 Alkynes: An Introduction to Organic Synthesis p. 151
Review Unit 3 p. 173
Chapter 9 Stereochemistry p. 176
Chapter 10 Alkyl Halides p. 205
Chapter 11 Reactions of Alkyl Halides: Nucleophilic Substitutions and Eliminations p. 224
Review Unit 4 p. 254
Chapter 12 Structure Determination: Mass Spectrometry and Infrared Spectroscopy p. 258
Chapter 13 Structure Determination: Nuclear Magnetic Resonance Spectroscopy p. 278
Review Unit 5 p. 302
Chapter 14 Conjugated Dienes and Ultraviolet Spectroscopy p. 305
Chapter 15 Benzene and Aromaticity p. 327
Chapter 16 Chemistry of Benzene: Electrophilic Aromatic Substitution p. 345
Review Unit 6 p. 381
Chapter 17 Alcohols and Phenols p. 385
Chapter 18 Ethers and Epoxides; Thiols and Sulfides p. 416
Review Unit 7 p. 442
Chapter 19 Aldehydes and Ketones: Nucleophilic Addition Reactions p. 445
Chapter 20 Carboxylic Acids p. 484
Chapter 21 Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution Reactions p. 506
Review Unit 8 p. 541
Chapter 22 Carbonyl Alpha-Substitution Reactions p. 545
Chapter 23 Carbonyl Condensation Reactions p. 570
Chapter 24 Amines p. 601
Review Unit 9 p. 635
Chapter 25 Biomolecules: Carbohydrates p. 638
Chapter 26 Biomolecules: Amino Acids, Peptides, and Proteins p. 663
Review Unit 10 p. 690
Chapter 27 Biomolecules: Lipids p. 693
Chapter 28 Biomolecules: Heterocycles and Nucleic Acids p. 713
Chapter 29 The Organic Chemistry of Metabolic Pathways p. 739
Review Unit 11 p. 761
Chapter 30 Orbitals and Organic Chemistry: Pericyclic Reactions p. 765
Chapter 31 Synthetic Polymers p. 786
Review Unit 12 p. 802
Appendices
Functional-Group Synthesis p. 805
Functional-Group Reactions p. 810
Reagents in Organic Chemistry p. 814
Name Reactions in Organic Chemistry p. 821
Abbreviations p. 829
Infrared Absorption Frequencies p. 832
Proton NMR Chemical Shifts p. 835
Top 40 Organic Chemicals p. 836
Nobel Prize Winners in Chemistry p. 838
Answers to Review-Unit Questions p. 846
Chapter 1 Structure and Bonding p. 1
Chapter 2 Polar Bonds and Their Consequences p. 17
Review Unit 1 p. 35
Chapter 3 Organic Compounds: Alkanes and Cycloalkanes p. 38
Chapter 4 Stereochemistry of Alkanes and Cycloalkanes p. 59
Chapter 5 An Overview of Organic Reactions p. 84
Review Unit 2 p. 100
Chapter 6 Alkenes: Structure and Reactivity p. 104
Chapter 7 Alkenes: Reactions and Synthesis p. 126
Chapter 8 Alkynes: An Introduction to Organic Synthesis p. 151
Review Unit 3 p. 173
Chapter 9 Stereochemistry p. 176
Chapter 10 Alkyl Halides p. 205
Chapter 11 Reactions of Alkyl Halides: Nucleophilic Substitutions and Eliminations p. 224
Review Unit 4 p. 254
Chapter 12 Structure Determination: Mass Spectrometry and Infrared Spectroscopy p. 258
Chapter 13 Structure Determination: Nuclear Magnetic Resonance Spectroscopy p. 278
Review Unit 5 p. 302
Chapter 14 Conjugated Dienes and Ultraviolet Spectroscopy p. 305
Chapter 15 Benzene and Aromaticity p. 327
Chapter 16 Chemistry of Benzene: Electrophilic Aromatic Substitution p. 345
Review Unit 6 p. 381
Chapter 17 Alcohols and Phenols p. 385
Chapter 18 Ethers and Epoxides; Thiols and Sulfides p. 416
Review Unit 7 p. 442
Chapter 19 Aldehydes and Ketones: Nucleophilic Addition Reactions p. 445
Chapter 20 Carboxylic Acids p. 484
Chapter 21 Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution Reactions p. 506
Review Unit 8 p. 541
Chapter 22 Carbonyl Alpha-Substitution Reactions p. 545
Chapter 23 Carbonyl Condensation Reactions p. 570
Chapter 24 Amines p. 601
Review Unit 9 p. 635
Chapter 25 Biomolecules: Carbohydrates p. 638
Chapter 26 Biomolecules: Amino Acids, Peptides, and Proteins p. 663
Review Unit 10 p. 690
Chapter 27 Biomolecules: Lipids p. 693
Chapter 28 Biomolecules: Heterocycles and Nucleic Acids p. 713
Chapter 29 The Organic Chemistry of Metabolic Pathways p. 739
Review Unit 11 p. 761
Chapter 30 Orbitals and Organic Chemistry: Pericyclic Reactions p. 765
Chapter 31 Synthetic Polymers p. 786
Review Unit 12 p. 802
Appendices
Functional-Group Synthesis p. 805
Functional-Group Reactions p. 810
Reagents in Organic Chemistry p. 814
Name Reactions in Organic Chemistry p. 821
Abbreviations p. 829
Infrared Absorption Frequencies p. 832
Proton NMR Chemical Shifts p. 835
Top 40 Organic Chemicals p. 836
Nobel Prize Winners in Chemistry p. 838
Answers to Review-Unit Questions p. 846
Organic chemistry / 5th ed.
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