化工热力学导论
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作 者：[美]史密斯（Smith.J.M.）、[美]范内斯（Van Ness,H.C.）、[美] 阿博特（Abbott,M.M.） 著，江振西 改编
分类号：
ISBN：9787122197894
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简介
Smith教授等编著的《化工热力学导论》是世界化工领域影响最大、发行范围最广的化工热力学教材。本书是根据英文原版书《化工热力学导论》第7版改编。 改编书选取了原书前13章，内容涵盖了化学工程师专业教育所必需的内容。全书主要内容包括以下几个方面：热力学基本概念和基本定律、纯流体的PVT性质、热效应、纯流体的热力学性质、热力学在流动过程中的应用、热力做功、制冷、汽液平衡、溶液热力学理论和应用以及化学反应平衡。这13章内容可以分为三部分：热力学和化学热力学基础，包括第1-6章；热力学在工业过程中的应用，包括第7-9章；热力学在化学过程中的应用，包括第10-13章。书中给出了大量既有理论意义，又切合工业实际的例题，并配有大量来自工业实践的习题。 全书行文流畅、图表丰富、通俗易懂。可作为化学工程与工艺专业以及其他相关专业的化工热力学教科书，也可以作为相关专业研究人员，工程设计和生产管理技术人员的重要参考书，也可以用作化工专业英语的教材或选读材料。
目录
List of Symbols
Preface
Chapter 1 Introduction
1.1 THE SCOPE OF THERMODYNAMICS
1.2 DIMENSIONS AND UNITS
1.3 MEASURES OF AMOUNT OR SIZE
1.4 FORCE
1.5 TEMPERATURE
1.6 PRESSURE
1.7 WORK
1.8 ENERGY
1.9 HEAT
KEY NOTES
GLOSSARY AND EXPLANATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 2 The First Law and Other Basic Concepts
2.1 JOULE’S EXPERIMENTS
2.2 INTERNAL ENERGY
2.3 THE FIRST LAW OF THERMODYNAMICS
2.4 ENERGY BALANCE FOR CLOSED SYSTEMS
2.5 THERMODYNAMIC STATE AND STATE FUNCTIONS
2.6 EQUILIBRIUM
2.7 THE PHASE RULE
2.8 THE REVERSIBLE PROCESS
2.9 CONSTANT-V AND CONSTANT-P PROCESSES
2.10 ENTHALPY
2.11 HEAT CAPACITY
2.12 MASS AND ENERGY BALANCES FOR OPEN SYSTEMS
KEY NOTES
GLOSSARY AND EXPLANATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 3 Volumetric Properties of Pure Fluids
3.1 PVT BEHAVIOR OF PURE SUBSTANCES
3.2 VIRIAL EQUATIONS OF STATE
3.3 THE IDEAL GAS
3.4 APPLICATION OF THE VIRIAL EQUATIONS
3.5 CUBIC EQUATIONS OF STATE
3.6 GENERALIZED CORRELATIONS FOR GASES
3.7 GENERALIZED CORRELATIONS FOR LIQUIDS
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 4 Heat Effects
4.1 SENSIBLE HEAT EFFECTS
4.2 LATENT HEATS OF PURE SUBSTANCES
4.3 STANDARD HEAT OF REACTION
4.4 STANDARD HEAT OF FORMATION
4.5 STANDARD HEAT OF COMBUSTION
4.6 TEMPERATURE DEPENDENCE OF ΔH
4.7 HEAT EFFECTS OF INDUSTRIAL REACTIONS
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 5 The Second Law of Thermodynamics
5.1 STATEMENTS OF THE SECOND LAW
5.2 HEAT ENGINES
5.3 THERMODYNAMIC TEMPERATURE SCALES
5.4 ENTROPY
5.5 ENTROPY CHANGES OF AN IDEAL GAS
5.6 MATHEMATICAL STATEMENT OF THE SECOND LAW
5.7 ENTROPY BALANCE FOR OPEN SYSTEMS
5.8 CALCULATION OF IDEAL WORK
5.9 LOST WORK
5.10 THE THIRD LAW OF THERMODYNAMICS
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 6 Thermodynamic Properties of Fluids
6.1 PROPERTY RELATIONS FOR HOMOGENEOUS PHASES
6.2 RESIDUAL PROPERTIES
6.3 RESIDUAL PROPERTIES BY EQUATIONS OF STATE
6.4 TWO-PHASE SYSTEMS
6.5 THERMODYNAMIC DIAGRAMS
6.6 TABLES OF THERMODYNAMIC PROPERTIES
6.7 GENERALIZED PROPERTY CORRELATIONS FOR GASES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 7 Applications of Thermodynamics to Flow Processes
7.1 DUCT FLOW OF COMPRESSIBLE FLUIDS
7.2 TURBINES (EXPANDERS)
7.3 COMPRESSION PROCESSES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 8 Production of Power from Heat
8.1 THE STEAM POWER PLANT
8.2 INTERNAL-COMBUSTION ENGINES
8.3 JET ENGINES，ROCKET ENGINES AND RAMJET ENGINES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 9 Refrigeration and Liquefaction
9.1 THE CARNOT REFRIGERATOR
9.2 THE VAPOR-COMPRESSION CYCLE
9.3 THE CHOICE OF REFRIGERANT
9.4 ABSORPTION REFRIGERATION
9.5 THE HEAT PUMP
9.6 LIQUEFACTION PROCESSES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 10 Vapor/Liquid Equilibrium: Introduction
10.1 THE NATURE OF EQUILIBRIUM
10.2 THE PHASE RULE; DUHEM’S THEOREM
10.3 VLE: QUALITATIVE BEHAVIOR
10.4 SIMPLE MODELS FOR VAPOR/LIQUID EQUILIBRIUM
10.5 VLE BY MODIFIED RAOULT’S LAW
10.6 VLE FROM K-VALUE CORRELATIONS
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 11 Solution Thermodynamics: Theory
11.1 FUNDAMENTAL PROPERTY RELATION
11.2 THE CHEMICAL POTENTIAL AND PHASE EQUILIBRIA
11.3 PARTIAL PROPERTIES
11.4 THE IDEAL-GAS MIXTURE MODEL
11.5 FUGACITY AND FUGACITY COEFFICIENT: PURE SPECIES
11.6 FUGACITY AND FUGACITY COEFFICIENT: SPECIES IN SOLUTION
11.7 GENERALIZED CORRELATIONS FOR THE FUGACITY COEFFICIENT
11.8 THE IDEAL-SOLUTION MODEL
11.9 EXCESS PROPERTIES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 12 Solution Thermodynamics: Applications
12.1 LIQUID-PHASE PROPERTIES FROM VLE DATA
12.2 MODELS FOR THE EXCESS GIBBS ENERGY
12.3 PROPERTY CHANGES OF MIXING
12.4 HEAT EFFECTS OF MIXING PROCESSES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 13 Chemical-Reaction Equilibria
13.1 THE REACTION COORDINATE
13.2 APPLICATION OF EQUILIBRIUM CRITERIA TO CHEMICAL REACTIONS
13.3 THE STANDARD GIBBS-ENERGY CHANGE AND THE EQUILIBRIUM
CONSTANT
13.4 EFFECT OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT
13.5 EVALUATION OF EQUILIBRIUM CONSTANTS
13.6 RELATION OF EQUILIBRIUM CONSTANTS TO COMPOSITION
13.7 EQUILIBRIUM CONVERSIONS FOR SINGLE REACTIONS
13.8 PHASE RULE AND DUHEM’S THEOREM FOR REACTING SYSTEMS
13.9 MULTIREACTION EQUILIBRIA
KEY NOTES
GLOSSARY AND EXPLAINATION
CONCEPTUAL PROBLEMS
PROBLEMS
Appendix A Conversion Factors and Values of the Gas Constant
Appendix B Properties of Pure Species
Appendix C Heat Capacities ad Property Changes of Formation
Appendix D Representative Computer Programs
参考文献
Preface
Chapter 1 Introduction
1.1 THE SCOPE OF THERMODYNAMICS
1.2 DIMENSIONS AND UNITS
1.3 MEASURES OF AMOUNT OR SIZE
1.4 FORCE
1.5 TEMPERATURE
1.6 PRESSURE
1.7 WORK
1.8 ENERGY
1.9 HEAT
KEY NOTES
GLOSSARY AND EXPLANATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 2 The First Law and Other Basic Concepts
2.1 JOULE’S EXPERIMENTS
2.2 INTERNAL ENERGY
2.3 THE FIRST LAW OF THERMODYNAMICS
2.4 ENERGY BALANCE FOR CLOSED SYSTEMS
2.5 THERMODYNAMIC STATE AND STATE FUNCTIONS
2.6 EQUILIBRIUM
2.7 THE PHASE RULE
2.8 THE REVERSIBLE PROCESS
2.9 CONSTANT-V AND CONSTANT-P PROCESSES
2.10 ENTHALPY
2.11 HEAT CAPACITY
2.12 MASS AND ENERGY BALANCES FOR OPEN SYSTEMS
KEY NOTES
GLOSSARY AND EXPLANATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 3 Volumetric Properties of Pure Fluids
3.1 PVT BEHAVIOR OF PURE SUBSTANCES
3.2 VIRIAL EQUATIONS OF STATE
3.3 THE IDEAL GAS
3.4 APPLICATION OF THE VIRIAL EQUATIONS
3.5 CUBIC EQUATIONS OF STATE
3.6 GENERALIZED CORRELATIONS FOR GASES
3.7 GENERALIZED CORRELATIONS FOR LIQUIDS
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 4 Heat Effects
4.1 SENSIBLE HEAT EFFECTS
4.2 LATENT HEATS OF PURE SUBSTANCES
4.3 STANDARD HEAT OF REACTION
4.4 STANDARD HEAT OF FORMATION
4.5 STANDARD HEAT OF COMBUSTION
4.6 TEMPERATURE DEPENDENCE OF ΔH
4.7 HEAT EFFECTS OF INDUSTRIAL REACTIONS
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 5 The Second Law of Thermodynamics
5.1 STATEMENTS OF THE SECOND LAW
5.2 HEAT ENGINES
5.3 THERMODYNAMIC TEMPERATURE SCALES
5.4 ENTROPY
5.5 ENTROPY CHANGES OF AN IDEAL GAS
5.6 MATHEMATICAL STATEMENT OF THE SECOND LAW
5.7 ENTROPY BALANCE FOR OPEN SYSTEMS
5.8 CALCULATION OF IDEAL WORK
5.9 LOST WORK
5.10 THE THIRD LAW OF THERMODYNAMICS
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 6 Thermodynamic Properties of Fluids
6.1 PROPERTY RELATIONS FOR HOMOGENEOUS PHASES
6.2 RESIDUAL PROPERTIES
6.3 RESIDUAL PROPERTIES BY EQUATIONS OF STATE
6.4 TWO-PHASE SYSTEMS
6.5 THERMODYNAMIC DIAGRAMS
6.6 TABLES OF THERMODYNAMIC PROPERTIES
6.7 GENERALIZED PROPERTY CORRELATIONS FOR GASES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 7 Applications of Thermodynamics to Flow Processes
7.1 DUCT FLOW OF COMPRESSIBLE FLUIDS
7.2 TURBINES (EXPANDERS)
7.3 COMPRESSION PROCESSES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 8 Production of Power from Heat
8.1 THE STEAM POWER PLANT
8.2 INTERNAL-COMBUSTION ENGINES
8.3 JET ENGINES，ROCKET ENGINES AND RAMJET ENGINES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 9 Refrigeration and Liquefaction
9.1 THE CARNOT REFRIGERATOR
9.2 THE VAPOR-COMPRESSION CYCLE
9.3 THE CHOICE OF REFRIGERANT
9.4 ABSORPTION REFRIGERATION
9.5 THE HEAT PUMP
9.6 LIQUEFACTION PROCESSES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 10 Vapor/Liquid Equilibrium: Introduction
10.1 THE NATURE OF EQUILIBRIUM
10.2 THE PHASE RULE; DUHEM’S THEOREM
10.3 VLE: QUALITATIVE BEHAVIOR
10.4 SIMPLE MODELS FOR VAPOR/LIQUID EQUILIBRIUM
10.5 VLE BY MODIFIED RAOULT’S LAW
10.6 VLE FROM K-VALUE CORRELATIONS
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 11 Solution Thermodynamics: Theory
11.1 FUNDAMENTAL PROPERTY RELATION
11.2 THE CHEMICAL POTENTIAL AND PHASE EQUILIBRIA
11.3 PARTIAL PROPERTIES
11.4 THE IDEAL-GAS MIXTURE MODEL
11.5 FUGACITY AND FUGACITY COEFFICIENT: PURE SPECIES
11.6 FUGACITY AND FUGACITY COEFFICIENT: SPECIES IN SOLUTION
11.7 GENERALIZED CORRELATIONS FOR THE FUGACITY COEFFICIENT
11.8 THE IDEAL-SOLUTION MODEL
11.9 EXCESS PROPERTIES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 12 Solution Thermodynamics: Applications
12.1 LIQUID-PHASE PROPERTIES FROM VLE DATA
12.2 MODELS FOR THE EXCESS GIBBS ENERGY
12.3 PROPERTY CHANGES OF MIXING
12.4 HEAT EFFECTS OF MIXING PROCESSES
KEY NOTES
GLOSSARY AND EXPLAINATIONS
CONCEPTUAL PROBLEMS
PROBLEMS
Chapter 13 Chemical-Reaction Equilibria
13.1 THE REACTION COORDINATE
13.2 APPLICATION OF EQUILIBRIUM CRITERIA TO CHEMICAL REACTIONS
13.3 THE STANDARD GIBBS-ENERGY CHANGE AND THE EQUILIBRIUM
CONSTANT
13.4 EFFECT OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT
13.5 EVALUATION OF EQUILIBRIUM CONSTANTS
13.6 RELATION OF EQUILIBRIUM CONSTANTS TO COMPOSITION
13.7 EQUILIBRIUM CONVERSIONS FOR SINGLE REACTIONS
13.8 PHASE RULE AND DUHEM’S THEOREM FOR REACTING SYSTEMS
13.9 MULTIREACTION EQUILIBRIA
KEY NOTES
GLOSSARY AND EXPLAINATION
CONCEPTUAL PROBLEMS
PROBLEMS
Appendix A Conversion Factors and Values of the Gas Constant
Appendix B Properties of Pure Species
Appendix C Heat Capacities ad Property Changes of Formation
Appendix D Representative Computer Programs
参考文献
化工热力学导论
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