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简介
本书介绍了电化学中常用的一些基本概念、基本原理及常用的研究地
,如循环伏安法、交流阻抗法、极谱法和脉冲伏安法,并介绍了电化学在
腐蚀防护和生物电化学中的应用。
本书可作为电化学专业的本科生教材,也可供从事电化学科学研究的
科研工作者和技术人员参考。
目录
1 Introduction
1.1 The Scope of Electrochemistry
1.2 The Nature ofElectrode Reactions
1.3 Thermodynamics and Kinetics
1.4 Methods for Studying Electrode Reactions
1.5 Applications of Eleetroeheraistry
2 Introduction to the Fundamental Concepts of Electrochemistry
2.1 Introduction
2.2 Electrochemical Cells and Reactions
2.3 Electron Transfer
2.4 Mass Transport
2.5 The Interaction d Electron Transfer and Mass Transport
2.6 Coupled Chemical Reactions
2.7 Adsorption
2.8 Phase Formation
3 Kinetics of Electrode Reactions
3.1 Intnxluefon
3.2 Essentials of Electrode Reactions
3.3 Bufle-Volmer Model of Electrode Kinetics
3.4 Implications of the Butler-Volmer Model for the One-step, One-electron Process
3.5 Multistep Mechanisms
4 The Electrical Double Layer
4.1 Introduction
4.2 The Thermodynamics of Charged Interfaces
4.3 The Statute d the Electrical Double Layer
4.4 The Adsorption Isotherm
4.5 The Effect of Doubly Layer Structure on Electrode Kinetics
4.6 Experimental Methods
5 Electrodamical Experiments
5.1 Introduction
5.2 Electro& Materials
5.3 The Working Electrode: Preparation and Cleaning
5.4 The CeU: Measurements at Equilibrium
5.5 The Cell: Measurements away from Equilihrium
5.6 Calibration of Electrodes and Cells
5.7 Insmanentation: General
5.8 Analgue Instrumentation
6 Potential Sweep Techniques and Cyclic Voltammetry
6.1 Introduction
6.2 Reversible Reactions
6.3 Irreversible Systems
6.4 Coupled Homogeneous Reactions
6.5 mnstrations of the Use of Cyclic Vohammetry for the Study of Coupled Chemical Reactions
6.6 Surface Processes
6.7 More Recent Developments
7 Polarography and Pulse Voltammetry
7.1 Introduction
7.2 Behavior at Polarographic Eleetredes
7.3 Pulse Voltammetry
8 Alternating Current Techniques
8.1 Introduction
8.2 A.C. Theory
8.3 Measuring the Impedance of an Electrochemical Cell
8.4 Applications of Impedance Analysis
9 Corrosion
9.1 Introduction
9.2 Fundamentals
9.3 Types of Metallic Corrosion
9.4 Electrochemical Methods of Avoiding Conrrsion
10 Bioelectrochemistry
10.1 Introduction
10.2 The Electrochemical Interfaeo between Biomoleeules
10.3 Nerve Impulse and Cardiovascular Electrochemistry
10.4 Oxidative Phesphorvlafion
10.5 Bioenergetics
10.6 Bioeleetrocatalysis
10.7 Bioelectroanalysis
10.8 Future Perspectives
Reference
1.1 The Scope of Electrochemistry
1.2 The Nature ofElectrode Reactions
1.3 Thermodynamics and Kinetics
1.4 Methods for Studying Electrode Reactions
1.5 Applications of Eleetroeheraistry
2 Introduction to the Fundamental Concepts of Electrochemistry
2.1 Introduction
2.2 Electrochemical Cells and Reactions
2.3 Electron Transfer
2.4 Mass Transport
2.5 The Interaction d Electron Transfer and Mass Transport
2.6 Coupled Chemical Reactions
2.7 Adsorption
2.8 Phase Formation
3 Kinetics of Electrode Reactions
3.1 Intnxluefon
3.2 Essentials of Electrode Reactions
3.3 Bufle-Volmer Model of Electrode Kinetics
3.4 Implications of the Butler-Volmer Model for the One-step, One-electron Process
3.5 Multistep Mechanisms
4 The Electrical Double Layer
4.1 Introduction
4.2 The Thermodynamics of Charged Interfaces
4.3 The Statute d the Electrical Double Layer
4.4 The Adsorption Isotherm
4.5 The Effect of Doubly Layer Structure on Electrode Kinetics
4.6 Experimental Methods
5 Electrodamical Experiments
5.1 Introduction
5.2 Electro& Materials
5.3 The Working Electrode: Preparation and Cleaning
5.4 The CeU: Measurements at Equilibrium
5.5 The Cell: Measurements away from Equilihrium
5.6 Calibration of Electrodes and Cells
5.7 Insmanentation: General
5.8 Analgue Instrumentation
6 Potential Sweep Techniques and Cyclic Voltammetry
6.1 Introduction
6.2 Reversible Reactions
6.3 Irreversible Systems
6.4 Coupled Homogeneous Reactions
6.5 mnstrations of the Use of Cyclic Vohammetry for the Study of Coupled Chemical Reactions
6.6 Surface Processes
6.7 More Recent Developments
7 Polarography and Pulse Voltammetry
7.1 Introduction
7.2 Behavior at Polarographic Eleetredes
7.3 Pulse Voltammetry
8 Alternating Current Techniques
8.1 Introduction
8.2 A.C. Theory
8.3 Measuring the Impedance of an Electrochemical Cell
8.4 Applications of Impedance Analysis
9 Corrosion
9.1 Introduction
9.2 Fundamentals
9.3 Types of Metallic Corrosion
9.4 Electrochemical Methods of Avoiding Conrrsion
10 Bioelectrochemistry
10.1 Introduction
10.2 The Electrochemical Interfaeo between Biomoleeules
10.3 Nerve Impulse and Cardiovascular Electrochemistry
10.4 Oxidative Phesphorvlafion
10.5 Bioenergetics
10.6 Bioeleetrocatalysis
10.7 Bioelectroanalysis
10.8 Future Perspectives
Reference
Engish in electrochemistry
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